Tetrakis(triphenylphosphane-κP)silver(I) trifluoroacetate ethanol monosolvate
نویسنده
چکیده
In the title solvated salt, [Ag(C18H15P)4](CF3CO2)·C2H5OH, the Ag(I) atom is coordinated by four P atoms from triphenyl-phosphane ligands in a distorted tetra-hedral geometry. The anion and solvent are engaged in weak O-H⋯O hydrogen bonds. Of the four triphenyl-phosphane ligands, two each have an equally disordered phenyl ring while the Ag(I) atom is disordered over two positions in a 0.9595 (15):0.0405 (15) ratio and the trifluoro-acetate anion is equally disordered over two positions with respect to the lattice ethanol mol-ecule.
منابع مشابه
Tetrakis(triphenylphosphane-κP)silver(I) trifluoromethanesulfonate dichloromethane monosolvate
In the title compound, [Ag(C(18)H(15)P)(4)]CF(3)O(3)S·CH(2)Cl(2), the Ag atom is coordinated by four P atoms from four PPh(3) ligands. The P-Ag-P angles are in the range 108.02 (6)-110.15 (6)°, which confirms the distorted tetra-hedral environment around the Ag atom.
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